PRODUCTS

ARCONATE HP

CAS NUMBER: 108-32-7

EC NUMBER: 203-572-1

MOLECULAR FORMULA: C4H6O3

MOLECULAR WEIGHT: 102.09

IUPAC NAME: 4-methyl-1,3-dioxolan-2-one

Arconate HP is a high purity cyclic carbonate
Arconate HP is used as a reactive diluent to reduce cost and to improve handling and processing properties in applications such as isocyanate (PMDI) adhesives and urethane adhesives.

Arconate HP reacts with amines to form carbamates.
Arconate HP undergoes hydroxy alkylation and trans esterification.

Arconate HP offers high boiling point and flash point
Arconate HP is a cyclic carbonate that reacts with amines to form carbamates, undergoes hydroxy alkylation and transesterification.

Arconate HP can be used as an isocyanate and unsaturated polyester resin cleanup solvent
Arconate HP is used as a viscosity reducer in coatings

Arconate HP is also used as a CO2 extraction solvent
Arconate HP is an electrolyte in lithium batteries

Arconate HP can be used as a polar additive for clay gellants
Arconate HP is also a foundry binder catalyst

Arconate HP can be used in textile dye carrier and cleaner
Arconate HP is an organic compound with the formula C4H6O3.

Arconate HP is a cyclic carbonate ester derived from propylene glycol.
This colorless and odorless liquid is useful as a polar, aprotic solvent.
Arconate HP is chiral, but is used as the racemic mixture in most contexts.

Preparation:
Although many organic carbonates are produced using phosgene, Arconate HP is exceptions.
They are mainly prepared by the carbonation of the epoxides (epoxypropane, or propylene oxide here):

CH3CHCH2O + CO2 → CH3C2H3O2CO

The process is particularly attractive since the production of these epoxides consumes carbon dioxide.
Thus this reaction is a good example of a green process.

The corresponding reaction of 1,2-propanediol with phosgene is complex, yielding not only Arconate HP but also oligomeric products.
Arconate HP can also be synthesized from urea and propylene glycol over zinc acetate.

APPLICATIONS:
As a solvent:
Arconate HP is used as a polar, aprotic solvent.
Arconate HP has a high molecular dipole moment (4.9 D), considerably higher than those of acetone (2.91 D) and ethyl acetate (1.78 D).
Arconate HP is possible, for example, to obtain potassium, sodium, and other alkali metals by electrolysis of their chlorides and other salts dissolved in propylene carbonate.

Electrolyte:
Due to its high relative permittivity (dielectric constant) of 64, it is frequently used as a high-permittivity component of electrolytes in lithium batteries, usually together with a low-viscosity solvent (e.g. dimethoxyethane).
Arconate HP's high polarity allows it to create an effective solvation shell around lithium ions, thereby creating a conductive electrolyte.

However, Arconate HP is not used in lithium-ion batteries due to its destructive effect on graphite.
Arconate HP can also be found in some adhesives, paint strippers, and in cosmetics.
Arconate HP is also used as plasticizer.
Arconate HP is also used as a solvent for removal of CO2 from natural gas and synthesis gas where H2S is not also present.

Other:
Arconate HP product may be converted to other carbonate esters by transesterification as well (see Carbonate ester#Carbonate transesterification).
In electrospray ionization mass spectrometry, Arconate HP is doped into low surface tension solutions to increase analyte charging.
In Grignard reaction Arconate HP (or most other carbonate esters) might be used to create tertiary alcohols

Arconate HP is a polar aprotic substance with very similar physicochemical characteristics to the organic solvents traditionally used for organic synthesis, such as acetonitrile and acetone.
Therefore, Arconate HP is beginning to be used as a “green” sustainable alternative solvent for chemical transformations.

Arconate HP is a non-corrosive colourless liquid with a high boiling point and low vapour pressure.
Arconate HP is biodegradable and economical, allowing its large-scale use.

USES:
Arconate HP is a VOC-free clear polar solvent having high boiling and flash points.
Arconate HP is a carbonate ester derived from propylene glycol with the peculiarity to have a low order of toxicity and a mild ether-like odor.

Arconate HP is stable under most conditions and it is not hydroscopic or corrosive.
Arconate HP is particularly well suited for applications requiring a water white product or high purity.

Arconate HP can be used in cosmetics and personal care products; mainly in the formulation of make-up, primarily lipstick, eye shadow, and mascara, as well as in skin cleansing products.
Arconate HP is used in a variety of syntheses and applications as a polar, aprotic solvent.
Arconate HP can also be found in some adhesives, paint strippers, cosmetics, and can be used as a plasticizer.

INDUSTRIAL USES:

-Adhesives and sealant chemicals

-Component in Li-ion electrolyte

-Intermediates

-Ion exchange agents

-Lubricants and lubricant additives

-Paint

-Paint additives and coating additives not described by other categories

-Photosensitive chemicals

-Plasticizers

-Solvents (which become part of product formulation or mixture)

Arconate HP can be synthesized from propylene oxide and CO2.
Optically active form of Arconate HP can be prepared from the reaction between CO2 and racemic epoxides.

Decomposition of Arconate HP on the graphite electrode in lithium batteries results in the formation of a lithium intercalated compound.
Arconate HP is a cyclic carbonate that is commonly used as a solvent and as a reactive intermediate in organic synthesis.

Arconate HP is being considered as a potential electrochemical solvent due to its low vapor pressure, high dielectric constant and high chemical stability.
Arconate HP may be used as a solvent for the asymmetric hydrogenation of nonfunctionalized olefins.

Arconate HP is an organic compound with the formula C4H6O3.
Arconate HP is a cyclic carbonate ester derived from propylene glycol.

This colorless and odorless liquid is useful as a polar, aprotic solvent.
Arconate HP is chiral, but is used exclusively as the racemic mixture in most contexts.

Key Benefits:
-Excellent performance in various applications

-Excellent NMP and NEP replacement

-Favorable safety, health, and environmental profile

PHYSICAL PROPERTIES:

-Molecular Weight: 102.09

-XLogP3: -0.4

-Exact Mass: 102.031694049

-Monoisotopic Mass: 102.031694049

-Topological Polar Surface Area: 35.5 Å²

-Physical Description: Colorless odorless liquid

-Color: Colorless

-Form: Liquid

-Odor: Odorless

-Boiling Point: 242.0 °C

-Melting Point: -48.8 °C

-Flash Point: 116 °C

-Solubility: 1.71 M

-Density: 1.2047 g/cu cm

-Vapor Pressure: 0.04 mmHg

-LogP: -0.41

-Refractive Index: 1.4189

-Chemical Classes: Other Classes -> Other Organic Compounds

Arconate HP is a superior polar organic solvent with high boil point.
Arconate HP can be used in spin dye printing, synthesis of polymer

CHEMICAL PROPERTIES:

-Hydrogen Bond Donor Count: 0

-Hydrogen Bond Acceptor Count: 3

-Rotatable Bond Count: 0

-Heavy Atom Count: 7

-Formal Charge: 0

-Complexity: 88.9

-Isotope Atom Count: 0

-Defined Atom Stereocenter Count: 0

-Undefined Atom Stereocenter Count: 1

-Defined Bond Stereocenter Count: 0

-Undefined Bond Stereocenter Count: 0

-Covalently-Bonded Unit Count: 1

-Compound Is Canonicalized: Yes

OTHER APPLICATIONS:

Paint & Coatings:
Arconate HP is used as a high-boiling solvent and film-forming auxiliary, especially in poly (vinyl fluoride) and poly (vinylidene fluoride) systems.
Arconate HP is also more eco-efficient compared to other solvents used in wire enamel coating applications.
As a reactive diluent, Arconate HP can reduce the viscosity of isocyanates or polyurethane pre-polymers in two-component polyurea systems.

Lithium-ion batteries and Electronics:
Arconate HP is another important cyclic carbonate solvent in lithium-ion batteries (LIB) electrolytes.
Due to its high dielectric constant, Arconate HP is used as a high permittivity component of electrolytes in lithium batteries, usually together with a low-viscosity solvent.
Arconate HP is also an effective circuit board and electronic cleaner.
Arconate HP is rapidly used in the computer, cell phones, hybrid and plug-in hybrid electric vehicle manufacturing markets.

Cleaning, Stripping and Degreasing:
Arconate HP has low toxicity and rapid biodegradability properties for solvents used in hard surface cleaning and degreasing formulations.
Alone or combined with other solvents, Arconate HP is effective as a polyurethane and polymer/resin cleaner, for cleaning up unsaturated polyester resins and gelcoats, as an all-purpose industrial and consumer cleaner, for cleaning stereolithographic parts, and as an ink cleaner.

Gas Treating and Petrochemical Applications:
Arconate HP is used as a physical solvent for removal of carbon dioxide (CO2) and hydrogen sulfide (H2S) in natural gas treating, oil pyrolysis gas, and synthetic ammonia conversion gas applications.
Arconate HP is also used as an oil solvent and as an extraction agent for olefins and aromatics.
In Grignard reactions, Arconate HP is used as an intermediate to create tertiary alcohols.

Other Uses and Applications:
Arconate HP is used as a binder for foundry sand molds, as a plasticizer for polymers, and in pesticide formulations.
In the textile industry can be used as synthetic fiber additives and fixatives, spinning solvents, or water-solvent dye pigment dispersant.
Arconate HP is not corrosive, therefore, it can be used in cosmetic and personal care products like make-up, antiperspirants, hair conditioners, and other products.

SYNONYMS:

108-32-7
4-Methyl-1,3-dioxolan-2-one
1,2-Propylene carbonate
1,2-Propanediol cyclic carbonate
1,3-Dioxolan-2-one, 4-methyl-
Cyclic propylene carbonate
Texacar PC
Arconate 5000
1,2-Propanediol carbonate
1-Methylethylene carbonate
Cyclic 1,2-propylene carbonate
Dipropylene carbonate
1,2-Propanediyl carbonate
4-Methyldioxalone-2
Propylene glycol cyclic carbonate
Cyclic methylethylene carbonate
4-Methyl-2-oxo-1,3-dioxolane
Carbonic acid, propylene ester
Carbonic acid, cyclic propylene ester
NSC 11784
Propylenester kyseliny uhlicite
Carbonic acid cyclic methylethylene ester
Propylene carbonate
Carbonic acid, cyclic propylene ether
Propylenester kyseliny uhlicite
4-methyl-1,3-dioxolane-2-one
Propylene carbonate
Propylene carbonate, 99.5%
CAS-108-32-7
Propylene carbonate, 99.5%, anhydrous, AcroSeal(R)
Propylene carbonate
Solvenon PC
propylen carbonate
MFCD00005385
Carbonic acid propylene
1, 3-Dioxolan-2-one, 4-methyl-
1,2-Propanediol cyclic carbonate
1,3-Dioxolan-2-one, 4-methyl-
4-Methyl-1,3-dioxol-2-one
4-Methyl-1,3-dioxolan-2-on
4-Methyl-1,3-dioxolan-2-one
4-Méthyl-1,3-dioxolan-2-one
4-Methyl-2-oxo-1,3-dioxolane
8D08K3S51E
Arconate 1000
Carbonic acid cyclic 1,2-propylene ester
Carbonic acid, cyclic propylene ether
Cyclic propylene carbonate
Propylene carbonate [Wiki]
Propylene glycol cyclic carbonate
(4S)-4-Methyl-1,3-dioxolan-2-one
(R)-4-Methyl-1,3-dioxolan-2-one
(S)-4-Methyl-1,3-dioxolan-2-one
1,2-PDC
1,2-PROPANEDIOL CARBONATE
1,2-Propanediyl carbonate
1,2-PROPYLENE CARBONATE
1,2-Propylene glycol carbonate
1,2-Propylene-d6 Carbonate
1-Methylethylene carbonate
2-(Piperidin-4-yl)acetonitrile
202480-74-8
2-Oxo-4-methyl-1,3-dioxolane
4-METHYL-1,3-DIOXOLANE-2-ONE
Arconate 5000
Arconate propylene carbonate
Carbonic acid cyclic methylethylene ester
Carbonic acid, cyclic propylene ester
Carbonic acid, propylene ester
CYCLIC 1,2-PROPYLENE CARBONATE
Cyclic methylethylene carbonate
Dipropylene carbonate
propylenecarbonate
Propylenester kyseliny uhlicite [Czech]
Propylenester kyseliny uhlicite
Solvenon PC
Texacar PC